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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
2-氯苯甲醛
合成路线
(共 849 条)
89-98-5
2-氯苯甲醛
→
反应条件
110605-11-3
反应条件
1: 75 percent / gl. acetic acid / ethanol / 5 h / Heating 2: 1) aq. NaNO2, gl. acetic acid, HCl / 1) 0-5 deg C, 2) pyridine, r.t., overnight View Scheme
参考文献
Singh, Shradha; Shukla, Mukundja; Srivastava, Vijai K.; Shanker, K.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987 , vol. 26, # 1-12 p. 368 - 370
89-98-5
2-氯苯甲醛
→
反应条件
110605-05-5
反应条件
1: 75 percent / gl. acetic acid / ethanol / 5 h / Heating 2: 1) aq. NaNO2, gl. acetic acid, HCl / 1) 0-5 deg C, 2) pyridine, r.t., overnight View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 26, # 1-12 p. 368 - 370
1377975-25-1
+
89-98-5
2-氯苯甲醛
→
反应条件
98288-14-3
+
110296-02-1
反应条件
1: (methoxycarbonylmethyl)methyldiphenylphosphonium chloride With potassium hexamethylsilazane in tetrahydrofuran Wittig reaction; 1 h; Inert atmosphere; 2: 2-chloro-benzaldehyde in tetrahydrofuran T=-78°C; Wittig reaction; Inert atmosphereCooling with acetone-dry ice; optical yield given as percent dediastereoselective reaction;
参考文献
Byrne, Peter A.; Gilheany, Declan G.
Journal of the American Chemical Society, 2012 , vol. 134, # 22 p. 9225 - 9239
89-98-5
2-氯苯甲醛
+
96-32-2
溴乙酸甲酯
→
反应条件
98288-14-3
+
110296-02-1
反应条件
(p-trifluoromethyl)phenylsilane; tris(n-octyl)phosphine oxide; N-ethyl-N,N-diisopropylamine; 4-nitro-benzoic acid in toluene T=100°C; Wittig Olefination; 24 h; Inert atmosphereSealed tubeSchlenk technique; Overall yield = 81 percent; Overall yield = 159 mg; diastereoselective reaction;
参考文献
O'Brien, Christopher J.; Lavigne, Florie; Coyle, Emma E.; Holohan, Andrew J.; Doonan, Bryan J.
Chemistry - A European Journal, 2013 , vol. 19, # 19 p. 5854 - 5858
89-98-5
2-氯苯甲醛
+
21204-67-1
→
反应条件
98288-14-3
+
110296-02-1
反应条件
in water T=20°C; Wittig reaction; 0.0833333 h; Title compound not separated from byproducts.;
参考文献
El-Batta, Amer; Jiang, Changchun; Zhao, Wen; Anness, Robert; Cooksy, Andrew L.; Bergdahl, Mikael
Journal of Organic Chemistry, 2007 , vol. 72, # 14 p. 5244 - 5259
89-98-5
2-氯苯甲醛
→
反应条件
105871-20-3
反应条件
1: LiAlH4 / diethyl ether / Heating View Scheme
参考文献
Bojarski, Andrzej J; Mokrosz, Maria J; Minol, Sijka Charakchieva; Koziol, Aneta; Wesolowska, Anna; Tatarczynska, Ewa; Klodzinska, Aleksandra; Chojnacka-Wojcik, Ewa
Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 1 p. 87 - 95
67-66-3
氯仿
+
89-98-5
2-氯苯甲醛
→
反应条件
10291-39-1
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene Addition; 4 h;
参考文献
Aggarwal, Varinder K.; Mereu, Andrea
Journal of Organic Chemistry, 2000 , vol. 65, # 21 p. 7211 - 7212
123-00-2
+
89-98-5
2-氯苯甲醛
→
反应条件
107922-87-2
反应条件
unter vermindertem Druck und Hydrieren des Reaktionsprodukts an Platin in Aethanol;
参考文献
Sen; Kulkarni
Journal of the Indian Chemical Society, 1958 , vol. 35, p. 205,208,209
89-98-5
2-氯苯甲醛
+
135-19-3
+
109-77-3
→
反应条件
111861-47-3
反应条件
L-proline in ethanol 6 h; Reflux;
参考文献
Behbahani, Farahnaz Kargar; Ghorbani, Mehdi; Sadeghpour, Mahdieh; Mirzaei, Mohamad
Letters in Organic Chemistry, 2013 , vol. 10, # 3 p. 191 - 194
89-98-5
2-氯苯甲醛
→
反应条件
104728-15-6
反应条件
1: 92 percent / ethanol / 6 h / Heating 2: 195 mg / K, ammonia, ferric nitrate / diethyl ether / 1 h View Scheme
参考文献
Sengupta, Dibyendu; Anand, Nitya
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 923 - 927
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