toluene-4-sulfonic acid in benzene 1 h; Heating;

1: 1.) n-BuLi / 1.) THF, -78 deg C, 1 h; 2.) -78 deg C, 1 h 2: 72 percent / tetrahydrofuran / 12 h / Ambient temperature 3: 92 percent / DIBAL / diethyl ether / 1.5 h / -30 °C 4: 86 percent / p-toluenesulfonic acid / benzene / 1 h / Heating View Scheme

1: 72 percent / tetrahydrofuran / 12 h / Ambient temperature 2: 92 percent / DIBAL / diethyl ether / 1.5 h / -30 °C 3: 86 percent / p-toluenesulfonic acid / benzene / 1 h / Heating View Scheme

1: 92 percent / DIBAL / diethyl ether / 1.5 h / -30 °C 2: 86 percent / p-toluenesulfonic acid / benzene / 1 h / Heating View Scheme