15,16-二氢-11-甲基环戊并(a)菲-17-酮合成路线 （共 7 条）
反应条件
1: 31 percent / pentafluoroiodosylbenzene / 5,10,15,20-tetrakis(pentafluorophenyl)porphyrinatoiron(III) chloride / CH2Cl2; methanol / Ambient temperature 2: aq. H2SO4 / 5 h / 100 °C View Scheme
参考文献
Harden, Grahame J.; Coombs, Maurice M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 23 p. 3037 - 3042
反应条件
palladium on activated charcoal in various solvent(s)
0.5 h; Heating;
参考文献
Lee, Hongmee; Harvey, Ronald G.
Journal of Organic Chemistry, 1988 , vol. 53, # 18 p. 4253 - 4256
反应条件
acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone
参考文献
Nandi, Sukumar; Panda, Kausik; Suresh; Ila, Hiriyakkanavar; Junjappa, Hiriyakkanavar
Tetrahedron, 2004 , vol. 60, # 16 p. 3663 - 3673
反应条件
1: 76 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / acetic acid; H2O / 0.5 h / Heating
2: 86 percent / 10percent Pd/C / various solvent(s) / 0.5 h / Heating
View Scheme
参考文献
Lee, Hongmee; Harvey, Ronald G.
Journal of Organic Chemistry, 1988 , vol. 53, # 18 p. 4253 - 4256
反应条件
1: 88 percent / Raney Nickel / ethanol / Heating
2: 4,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,2-dicarbonitrile; acetic acid
View Scheme
参考文献
Nandi, Sukumar; Panda, Kausik; Suresh; Ila, Hiriyakkanavar; Junjappa, Hiriyakkanavar
Tetrahedron, 2004 , vol. 60, # 16 p. 3663 - 3673
反应条件
(i), (ii) aq. HCl, PhNO2; Multistep reaction;
参考文献
Coombs,M.M.
Journal of the Chemical Society [Section] C: Organic, 1966 , p. 955 - 962
反应条件
1: (i), (ii) aq. HCl, NH4Cl
2: H2 / Adams catalyst
View Scheme
参考文献
Coombs,M.M.
Journal of the Chemical Society [Section] C: Organic, 1966 , p. 963 - 968
