反应条件
1: 42 percent / K2CO3, 18-crown-6 / benzene / 0.67 h / 56 °C
2: 97 percent / NaBH4, CeCl3*7H2O / methanol / 0.17 h / 0 - 5 °C
3: 100 percent / Et3N / CH2Cl2 / 0.17 h / -5 - 0 °C
4: 74 percent / LiN3, P(NMe2)3 / dimethylsulfoxide / Ambient temperature
5: H2 / Lindlar's catalyst / butan-1-ol / 3 h / 760 Torr
6: Et3N / butan-1-ol / 20 h / Heating
7: conc. HCl / 42 h / Ambient temperature
8: 70 percent / liquid NH3 / methanol / 18 h / 60 °C
9: 50 percent / 1 M BCl3 / CH2Cl2; hexane / 2.5 h / -75 °C
View Scheme
参考文献
Lim, Mu-ill; Marquez, Victor E.
Tetrahedron Letters, 1983 , vol. 24, # 50 p. 5559 - 5562
