(R)-(-)-1-苄氧基-2-丙醇合成路线 （共 11 条）
反应条件
toluene-4-sulfonic acid in methanol T=0 - 20°C;
参考文献
Chemistry - An Asian Journal, , vol. 6, # 1 p. 149 - 156
反应条件
[14C]-Sucrose in ethanol T=30°C; 144 h; bakers' yeast;
参考文献
Synthesis, , # 11 p. 1007 - 1009
反应条件
4-(N,N-dimethlyamino)pyridine; potassium hydroxide; triethylamine in dichloromethane
反应条件
tetrabutylammomium bromide; bis(tri-n-butyltin)oxide in benzene 16 h; Heating;
参考文献
Agricultural and Biological Chemistry, , vol. 50, # 9 p. 2261 - 2272
反应条件
1: 1.) n-BuLi / 1.) THF, hexane, 0 deg C, 30 min, 2.) 1.5 h. 2: 89 percent / Raney-Ni (W-2), NaPH2O2 / ethanol; H2O / 0.5 h / Ambient temperature; pH=5.2 View Scheme
参考文献
Tetrahedron, , vol. 53, # 38 p. 12883 - 12894
反应条件
1: 92 percent / mercuric sulphate, aq. H2SO4 / methanol / 2 h / 70 °C 2: 76 percent / sucrose / aq. ethanol / 144 h / 30 °C / bakers' yeast View Scheme
参考文献
Synthesis, , # 11 p. 1007 - 1009
反应条件
1: 1.) KOH, hexadecyltributylphosphonium bromide / 1.) C6H6, room temp., 15 min, 2.) 70 deg C, 3 h 2: 92 percent / mercuric sulphate, aq. H2SO4 / methanol / 2 h / 70 °C 3: 76 percent / sucrose / aq. ethanol / 144 h / 30 °C / bakers' yeast View Scheme
参考文献
Synthesis, , # 11 p. 1007 - 1009
反应条件
Wilkinson's catalyst; triethylamine Inert atmosphere;
参考文献
Organic and Biomolecular Chemistry, , vol. 10, # 34 p. 6930 - 6936,7
反应条件
in water T=30°C; 48 h; sucrose, Baker's yeast; Title compound not separated from byproducts;
参考文献
Acta chemica Scandinavica (Copenhagen, Denmark : 1989), , vol. 48, # 6 p. 506 - 510
反应条件
Dowex 50 X 8 (H+); ammonia; sodium hydride 1.) mineral oil, DMF, 0 deg C, 1 h; room temperature, 48 h, 2.) MeOH, 2 h, 3.) 70percent aq. MeOH, reflux, 4 h; Yield given. Multistep reaction;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 60, # 8 p. 1390 - 1409
