[(S)-C10H14ClNPd]2; Ag-(S)-TRIP in chloroform T=20 - 35°C; Overman rearrangement; Inert atmosphereDarkness; optical yield given as percent eeenantioselective reaction;

bis-μ-chloro-{(Rp)-2-[(4S,5S)-1,5-dimethyl-4-phenyl-4,5-dihydro-1H-imidazolyl]pentaphenylferrocenyl}dipalladium; N,N,N',N'-tetra-methylnaphthalene-1,8-diamine; silver nitrate in dichloromethane T=40°C; Aza-Claisen rearrangement; 20 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;