1-苯基-3-三甲基硅烷-2-丙炔-1-醇合成路线 （共 25 条）
反应条件
anhydrous iron chloride in toluene
0.7 h; Reflux; regioselective reaction;
参考文献
Ji, Wen-Hua; Pan, Ying-Ming; Zhao, Su-Yan; Zhan, Zhuang-Ping
Synlett, 2008 , # 19 p. 3046 - 3052
反应条件
Bi(NO3)3·5H2O; 3-butyl-1-ethyl-4-nitroimidazolium bis(trifluoromethylsulfonyl)imide
T=20 - 45°C; 4.16667 h; Inert atmosphere;
参考文献
Aridoss, Gopalakrishnan; Laali, Kenneth K.
Tetrahedron Letters, 2011 , vol. 52, # 51 p. 6859 - 6864
反应条件
hydrogen; dodecacarbonyltetrarhodium(0) in tetrahydrofuran
T=90°C; P=3000.24 Torr; 3 h;
参考文献
Fukuta, Yukimasa; Matsuda, Isamu; Itoh, Kenji
Tetrahedron Letters, 2001 , vol. 42, # 7 p. 1301 - 1304
反应条件
1: potassium carbonate / methanol / 1 h / 20 °C / Inert atmosphere
2: N,N,N',N,-tetramethylethylenediamine; oxygen; copper(l) chloride / acetone / 2 h / 20 °C
3: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 4 h / 60 °C / Inert atmosphere
View Scheme
参考文献
Wang, Ya-Hui; Liu, Heng; Zhu, Li-Li; Li, Xiao-Xiao; Chen, Zili
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 5 p. 707 - 712
反应条件
1: methanol; potassium carbonate / 2 h / 20 °C
2: dichloro(pyridine-2-carboxylato)gold(III); silver hexafluoroantimonate / 0.67 h / 50 °C / Molecular sieve
View Scheme
参考文献
Xu, Cheng-Fu; Xu, Mei; Yang, Liu-Qing; Li, Chuan-Ying
Journal of Organic Chemistry, 2012 , vol. 77, # 6 p. 3010 - 3016
