雄甾-1,4-二烯-3,17-二酮 合成路线 (共 75 条)
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反应条件
110325-37-6 (7R,8R,9S,10R,13S,14S)-7-(4-氨基苯基)硫基-10,13-二甲基-7,8,9,11,12,14,15,16-八氢-6H-环戊二烯并[a]菲-3,17-二酮
反应条件
sodium Yield given. Yields of byproduct given;
参考文献
Steroids, , vol. 50, # 1-3 p. 163 - 178
反应条件
1: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 2: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 3: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction View Scheme
参考文献
Journal of Steroid Biochemistry and Molecular Biology, , vol. 119, # 3-5 p. 161 - 170
反应条件
1: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 2: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction View Scheme
参考文献
Journal of Steroid Biochemistry and Molecular Biology, , vol. 119, # 3-5 p. 161 - 170
参考文献
Hershberg; Rubin; Schwenk
Journal of Organic Chemistry, 1950 , vol. 15, p. 292,295
Full Text Show Details
Schering A.G.
Patent: DE751739 , 1935 ;
DRP/DRBP Org.Chem.
反应条件
mineral oil T=530°C; in ein mit Glasperlen beschicktes Rohr;
参考文献
Inhoffen in H. Lettre; H. H. Inhoffen; R. Tschesche
Ueber Sterine, Gallensaeuren und verwandte Naturstoffe, 2. Aufl. Bd. 2 <Stuttgart 1959> S. 642, 643
Full Text Show Details
Hershberg; Rubin; Schwenk
Journal of Organic Chemistry, 1950 , vol. 15, p. 292,295
反应条件
1: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 2: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction View Scheme
参考文献
Verheyden; Noppe; Zorn; Van Immerseel; Bussche, J. Vanden; Wille; Bekaert; Janssen; De Brabander; Vanhaecke
Journal of Steroid Biochemistry and Molecular Biology, 2010 , vol. 119, # 3-5 p. 161 - 170
反应条件
T=25°C; 72 h; stereoselective reduction in the biotransformation by cell suspension cultures of Marchantia Polymorpha, other androsterone derivative;
参考文献
Verheyden; Noppe; Zorn; Van Immerseel; Bussche, J. Vanden; Wille; Bekaert; Janssen; De Brabander; Vanhaecke
Journal of Steroid Biochemistry and Molecular Biology, 2010 , vol. 119, # 3-5 p. 161 - 170
反应条件
1.1: toluene / 2 h / |Reflux 1.2: 1 h 2.1: copper(l) chloride / ethanol / 2 h / 20 °C / |Inert atmosphere 2.2: 20 °C / |Inert atmosphere 2.3: 20 °C View Scheme
参考文献
Wang, Chunli; Chen, Xiaoyu; Huang, Yaoqing; Yang, Jesse; Chen, Ying
Steroids, 2013 , vol. 78, # 14 p. 1339 - 1346
反应条件
toluene-4-sulfonic acid; ethylene glycol; benzene
参考文献
Gentles et al.
Journal of the American Chemical Society, 1958 , vol. 80, p. 3702,3704
反应条件
toluene-4-sulfonic acid
参考文献
Searle and Co.
Patent: US2875215 , 1957 ;