雄甾-1,4-二烯-3,17-二酮合成路线 （共 75 条）
反应条件
hydrogen; Cu/Al2O3 in toluene T=60°C; P=760 Torr;
参考文献
Journal of Organic Chemistry, , vol. 56, # 13 p. 4329 - 4333
反应条件
hydrogen; (.eta.4-1,5-cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate in dichloromethane 18 h;
参考文献
Suggs, J. William; Cox. S. D.; Crabtree, Robert H.; Quirk, Jennifer M.
Tetrahedron Letters, 1981 , vol. 22, p. 303 - 306
反应条件
hydrogen; Wilkinson's catalyst in benzene T=20°C; 2 h; Yield given;
参考文献
Goncharova, N. M.; Grinenko, G. S.
Pharmaceutical Chemistry Journal, 1980 , vol. 14, # 4 p. 245 - 246
Khimiko-Farmatsevticheskii Zhurnal, 1980 , vol. 14, # 4 p. 61 - 63
反应条件
diethyl-1,4-dihydro-2,6-dimethyl-3,5-pyridine dicarboxylate; 5 palladium on charcoal in ethanol 22 h; Reflux; stereoselective reaction;
参考文献
Ramachary, Dhevalapally B.; Sakthidevi, Rajasekar; Reddy, P. Srinivasa
RSC Advances, 2013 , vol. 3, # 32 p. 13497 - 13506
反应条件
1: diethyl-1,4-dihydro-2,6-dimethyl-3,5-pyridine dicarboxylate; 5 palladium on charcoal / ethanol / 22 h / |Reflux 2: diethyl-1,4-dihydro-2,6-dimethyl-3,5-pyridine dicarboxylate; C9H18N2*C10H16O4S / acetonitrile / 72 h / |Reflux View Scheme
参考文献
Ramachary, Dhevalapally B.; Sakthidevi, Rajasekar; Reddy, P. Srinivasa
RSC Advances, 2013 , vol. 3, # 32 p. 13497 - 13506
反应条件
Fusarium oxysporum SC1301 in dimethyl sulfoxide T=30°C; 15 h;
参考文献
Zhang, Hongliu; Ren, Jie; Wang, Yu; Sheng, Cuo; Wu, Qiaqing; Diao, Aipo; Zhu, Dunming
Tetrahedron, 2013 , vol. 69, # 1 p. 184 - 189
反应条件
336 h; Rhodotorula mucilaginosa;
参考文献
Draczynska, Bozena; Tlomak, Elzbieta; Dmochowska-Gladysz, Jadwiga; Siewinski, Antoni
Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, 1982 , vol. 30, # 1-12 p. 13 - 21
反应条件
phosphate buffer; Beauveria sp. culture T=28°C; 24 h;
参考文献
Pharmaceutical Chemistry Journal, , vol. 23, # 4 p. 352 - 355
Khimiko-Farmatsevticheskii Zhurnal, , # 4 p. 471 - 473
反应条件
sodium tetrahydroborate in ethanol; water T=22°C; 0.25 h; Title compound not separated from byproducts;
参考文献
Leontjev; Vasiljeva; Pivnitsky
Russian Chemical Bulletin, 2004 , vol. 53, # 3 p. 703 - 708
反应条件
T=25°C; 72 h; stereoselective reduction in the biotransformation by cell suspension cultures of Marchantia Polymorpha, other androsterone derivative;
参考文献
Verheyden; Noppe; Zorn; Van Immerseel; Bussche, J. Vanden; Wille; Bekaert; Janssen; De Brabander; Vanhaecke
Journal of Steroid Biochemistry and Molecular Biology, 2010 , vol. 119, # 3-5 p. 161 - 170
