2-甲基-5-硝基三氟甲苯合成路线 （共 13 条）
反应条件
copper(l) iodide in 1-methyl-pyrrolidin-2-one T=160°C; 4 h;
参考文献
EP1840122 A1, ;
Page/Page column 12-13 ;
反应条件
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; water; caesium carbonate in tetrahydrofuran Suzuki coupling reaction; Heating;
参考文献
Molander, Gary A.; Yun, Chang-Soo; Ribagorda, Maria; Biolatto, Betina
Journal of Organic Chemistry, 2003 , vol. 68, # 14 p. 5534 - 5539
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in 1,4-dioxane; water Suzuki-Miyaura coupling; 24 h; Heating;
参考文献
Gray; Andrews; Hook; Kitteringham; Voyle
Tetrahedron Letters, 2000 , vol. 41, # 32 p. 6237 - 6240
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in 1,4-dioxane Suzuki-Miyaura coupling; 23 h; Heating;
参考文献
Gray; Andrews; Hook; Kitteringham; Voyle
Tetrahedron Letters, 2000 , vol. 41, # 32 p. 6237 - 6240
反应条件
1: PCl5, POCl3 / 155 - 165 °C 2: SbF3 3: H2SO4, HNO3 4: aq. NH3 / 150 °C 5: (i) NaNO2, aq. HCl, (ii) NaH2PO2 View Scheme
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 33, # 9 p. 3031 - 3035,2957 - 2960
反应条件
1: H2SO4, HNO3 2: aq. NH3 / 150 °C 3: (i) NaNO2, aq. HCl, (ii) NaH2PO2 View Scheme
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 33, # 9 p. 3031 - 3035,2957 - 2960
反应条件
1: SbF3 2: H2SO4, HNO3 3: aq. NH3 / 150 °C 4: (i) NaNO2, aq. HCl, (ii) NaH2PO2 View Scheme
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 33, # 9 p. 3031 - 3035,2957 - 2960
反应条件
1: aq. NH3 / 150 °C 2: (i) NaNO2, aq. HCl, (ii) NaH2PO2 View Scheme
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 33, # 9 p. 3031 - 3035,2957 - 2960
反应条件
(i) NaNO2, aq. HCl, (ii) NaH2PO2; Multistep reaction;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 33, # 9 p. 3031 - 3035,2957 - 2960
反应条件
potassium permanganate
参考文献
Yagupol'skii,L.M.; Matyushecheva,G.I.
J. Gen. Chem. USSR (Engl. Transl.), 1963 , vol. 33, # 9 p. 3031 - 3035,2957 - 2960
