1: diisobutylaluminium hydride / diethyl ether / 1 h / -78 °C / |Inert atmosphere 2: sodium tetrahydroborate / tetrahydrofuran; water / 0.5 h / 0 °C / |Inert atmosphere 3: 1H-imidazole; triphenylphosphine; iodine / tetrahydrofuran / 2 h / 20 °C / |Inert atmosphere 4: cerium(III) chloride heptahydrate; sodium iodide / acetonitrile / 20 °C / |Inert atmosphere 5: neat (no solvent) / 2 h / 80 °C / |Inert atmosphere 6: tris-(dibenzylideneacetone)dipalladium(0); diethylamine; 1,2-bis-(diphenylphosphino)ethane / tetrahydrofuran / 20 °C / |Inert atmosphere 7: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 8: |Inert atmosphere View Scheme

1: 1H-imidazole; triphenylphosphine; iodine / tetrahydrofuran / 2 h / 20 °C / |Inert atmosphere 2: cerium(III) chloride heptahydrate; sodium iodide / acetonitrile / 20 °C / |Inert atmosphere 3: neat (no solvent) / 2 h / 80 °C / |Inert atmosphere 4: tris-(dibenzylideneacetone)dipalladium(0); diethylamine; 1,2-bis-(diphenylphosphino)ethane / tetrahydrofuran / 20 °C / |Inert atmosphere 5: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 6: |Inert atmosphere View Scheme

1: potassium carbonate / N,N-dimethyl-formamide / |Inert atmosphere 2: 4-(N,N-dimethlyamino)pyridine / acetonitrile / 20 °C / |Inert atmosphere 3: diisobutylaluminium hydride / diethyl ether / 1 h / -78 °C / |Inert atmosphere 4: sodium tetrahydroborate / tetrahydrofuran; water / 0.5 h / 0 °C / |Inert atmosphere 5: 1H-imidazole; triphenylphosphine; iodine / tetrahydrofuran / 2 h / 20 °C / |Inert atmosphere 6: cerium(III) chloride heptahydrate; sodium iodide / acetonitrile / 20 °C / |Inert atmosphere 7: neat (no solvent) / 2 h / 80 °C / |Inert atmosphere 8: tris-(dibenzylideneacetone)dipalladium(0); diethylamine; 1,2-bis-(diphenylphosphino)ethane / tetrahydrofuran / 20 °C / |Inert atmosphere 9: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 10: |Inert atmosphere View Scheme

1: cerium(III) chloride heptahydrate; sodium iodide / acetonitrile / 20 °C / |Inert atmosphere 2: neat (no solvent) / 2 h / 80 °C / |Inert atmosphere 3: tris-(dibenzylideneacetone)dipalladium(0); diethylamine; 1,2-bis-(diphenylphosphino)ethane / tetrahydrofuran / 20 °C / |Inert atmosphere 4: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 5: |Inert atmosphere View Scheme

1: sodium tetrahydroborate / tetrahydrofuran; water / 0.5 h / 0 °C / |Inert atmosphere 2: 1H-imidazole; triphenylphosphine; iodine / tetrahydrofuran / 2 h / 20 °C / |Inert atmosphere 3: cerium(III) chloride heptahydrate; sodium iodide / acetonitrile / 20 °C / |Inert atmosphere 4: neat (no solvent) / 2 h / 80 °C / |Inert atmosphere 5: tris-(dibenzylideneacetone)dipalladium(0); diethylamine; 1,2-bis-(diphenylphosphino)ethane / tetrahydrofuran / 20 °C / |Inert atmosphere 6: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 7: |Inert atmosphere View Scheme

1: neat (no solvent) / 2 h / 80 °C / |Inert atmosphere 2: tris-(dibenzylideneacetone)dipalladium(0); diethylamine; 1,2-bis-(diphenylphosphino)ethane / tetrahydrofuran / 20 °C / |Inert atmosphere 3: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 4: |Inert atmosphere View Scheme

1: tris-(dibenzylideneacetone)dipalladium(0); diethylamine; 1,2-bis-(diphenylphosphino)ethane / tetrahydrofuran / 20 °C / |Inert atmosphere 2: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 3: |Inert atmosphere View Scheme

1: potassium phosphate / chlorobenzene / 15 h / 90 °C / |Inert atmosphere 2: |Inert atmosphere View Scheme

chiral HPLC in hexane; isopropyl alcohol Resolution of racemate;

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