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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1-溴代萘
合成路线
(共 840 条)
90-11-9
1-溴代萘
+
882-33-7
二苯二硫醚
→
反应条件
7570-98-1
+
7570-96-9
反应条件
potassium tert-butylate in dimethyl sulfoxide T=40 - 80°C; Overall yield = 76 percent; Overall yield = 0.18 g;
参考文献
Kumar, Sangit; Kumar, Amit; Bhakuni, Bhagat Singh; Prasad, Ch. Durga; Kumar, Shailesh
Tetrahedron, 2013 , vol. 69, # 26 p. 5383 - 5392
90-11-9
1-溴代萘
+
7664-41-7
氨气
+
930-69-8
苯硫酚钠
→
反应条件
7570-98-1
+
7570-96-9
反应条件
Product distribution;
参考文献
Bunnett, Brotherton
Journal of Organic Chemistry, 1958 , vol. 23, p. 904
90-11-9
1-溴代萘
+
108-98-5
硫酚
→
反应条件
7570-98-1
反应条件
CyPF-tBu; palladium diacetate; sodium t-butanolate in ethylene glycol dimethyl ether T=110°C; 2 h; Inert atmosphere;
参考文献
Fernandez-Rodriguez, Manuel A.; Hartwig, John F.
Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1664 - 1672
90-11-9
1-溴代萘
+
930-69-8
苯硫酚钠
→
反应条件
7570-98-1
反应条件
o-phenylene-bislt;diphenylphosphinogt;-nickel(II) bromide in ethylene glycol T=200°C; 24 h;
参考文献
Cristau, H. J.; Chabaud, B.; Chene, A.; Christol, H.
Synthesis, 1981 , # 11 p. 892 - 894
90-11-9
1-溴代萘
+
882-33-7
二苯二硫醚
→
反应条件
7570-98-1
反应条件
[2,2']bipyridinyl; copper(l) iodide; magnesium in N,N-dimethyl-formamide T=200°C; 7 h; microwave irradiation;
参考文献
Kumar, Sangit; Engman, Lars
Journal of Organic Chemistry, 2006 , vol. 71, # 14 p. 5400 - 5403
90-11-9
1-溴代萘
+
882-33-7
二苯二硫醚
→
反应条件
7570-98-1
+
7570-96-9
反应条件
potassium tert-butylate in dimethyl sulfoxide T=40 - 80°C; Overall yield = 76 percent; Overall yield = 0.18 g;
参考文献
Kumar, Sangit; Kumar, Amit; Bhakuni, Bhagat Singh; Prasad, Ch. Durga; Kumar, Shailesh
Tetrahedron, 2013 , vol. 69, # 26 p. 5383 - 5392
591-50-4
碘苯
+
90-11-9
1-溴代萘
→
反应条件
7570-98-1
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; potassium phosphate; bis(dibenzylideneacetone)-palladium(0); thiolacetic acid potassium salt in acetone; toluene T=70 - 110°C; 9 h; Inert atmosphere;
参考文献
Park, Namjin; Park, Kyungho; Jang, Mihee; Lee, Sunwoo
Journal of Organic Chemistry, 2011 , vol. 76, # 11 p. 4371 - 4378
→
反应条件
7570-98-1
反应条件
palladium diacetate; N-ethyl-N,N-diisopropylamine; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in N,N-dimethyl-formamide T=100°C; 4 h; Inert atmosphere;
参考文献
Lee, Jae-Young; Phil, Ho Lee
Journal of Organic Chemistry, 2008 , vol. 73, # 18 p. 7413 - 7416
623-03-0
对氯苯甲腈
+
90-11-9
1-溴代萘
→
反应条件
7570-98-1
+
51238-46-1
反应条件
copper(l) iodide; sodium t-butanolate in acetonitrile T=0°C; 10 h; Sealed tubeIrradiationInert atmosphere;
参考文献
Uyeda, Christopher; Tan, Yichen; Fu, Gregory C.; Peters, Jonas C.
Journal of the American Chemical Society, 2013 , vol. 135, # 25 p. 9548 - 9552
13133-62-5
+
90-11-9
1-溴代萘
→
反应条件
7570-98-1
反应条件
lithium perchlorate in dimethyl sulfoxide other solvent; Rate constant;
参考文献
Amatore, Christian; Oturan, Mehmet A.; Pinson, Jean; Saveant, Jean-Michel; Thiebault, Andre
Journal of the American Chemical Society, 1985 , vol. 107, p. 3451 - 3459
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