反应条件
1: 1.) butyl-lithium, N,N,N',N'-tetramethyl-ethylenediamine / 1.) THF, -40 deg C, 1 h 2.) THF, -60 deg C, 30 min then warming to room temp. during 12 h
2: 96 percent / peracetic acid / CH2Cl2 / 1.) 0 deg C, 90 min 2.) 16 h, room temp.
3: 1.) butyl lithium / 1.) DME, -78 deg C, hexane, 20 min 2.) neat or DME, room temp.
View Scheme
参考文献
Craig, Donald; Ley, Steven V.; Simpkins, Nigel S.; Whitham, Gordon H.; Prior, Michael J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1949 - 1952
