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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
905966-40-7
合成路线
(共 26 条)
905966-40-7
→
反应条件
705254-34-8
(4-甲氧羰基苯基)三氟硼酸钾
反应条件
potassium hydrogen difluoride in tetrahydrofuran 1 h; Inert atmosphere;
参考文献
THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA
Patent: WO2009/137322 A2, 2009 ;
Location in patent: Page/Page column 19 ;
905966-40-7
+
19013-30-0
4-甲氧基苯基甲磺酸
→
反应条件
729-17-9
4’-甲氧基[1,1’-联苯]-4-甲酸甲酯
反应条件
potassium phosphate; Ni(COD)2; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 8 h; Inert atmosphere;
参考文献
THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA
Patent: WO2009/137322 A2, 2009 ;
Location in patent: Page/Page column 21; 29 ;
905966-40-7
+
696-62-8
4-碘苯甲醚
→
反应条件
729-17-9
4’-甲氧基[1,1’-联苯]-4-甲酸甲酯
反应条件
potassium phosphate; NiCl2(dppe); 1,2-bis-(diphenylphosphino)ethane in 1,4-dioxane T=110°C; Suzuki-Miyaura cross-coupling; 18 h; Inert atmosphere;
参考文献
Rosen, Brad M.; Huang, Chenghong; Percec, Virgil
Organic Letters, 2008 , vol. 10, # 12 p. 2597 - 2600
905966-40-7
+
104-92-7
4-溴苯甲醚
→
反应条件
729-17-9
4’-甲氧基[1,1’-联苯]-4-甲酸甲酯
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; 2-dicyclohexylphosphino-1,1'-biphenyl in 1,4-dioxane T=110°C; Inert atmosphere;
参考文献
THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA
Patent: WO2009/137322 A2, 2009 ;
Location in patent: Page/Page column 21; 22; 29; 30; 31 ;
905966-40-7
+
1138-62-1
→
反应条件
729-17-9
4’-甲氧基[1,1’-联苯]-4-甲酸甲酯
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 12 h; Inert atmosphere;
参考文献
Leowanawat, Pawaret; Zhang, Na; Resmerita, Ana-Maria; Rosen, Brad M.; Percec, Virgil
Journal of Organic Chemistry, 2011 , vol. 76, # 24 p. 9946 - 9955
905966-40-7
+
124-38-9
二氧化碳
→
反应条件
1679-64-7
对苯二甲酸单甲酯
反应条件
potassium tert-butylate; copper(l) chloride; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in tetrahydrofuran T=70°C; P=760.051 Torr; 24 h;
参考文献
Ohishi, Takeshi; Nishiura, Masayoshi; Hou, Zhaomin
Angewandte Chemie - International Edition, 2008 , vol. 47, # 31 p. 5792 - 5795
905966-40-7
+
90-11-9
1-溴代萘
→
反应条件
229467-26-9
4-(萘-1-基)苯甲酸甲酯
反应条件
palladium diacetate; cesium fluoride; 2-dicyclohexylphosphino-1,1'-biphenyl in 1,4-dioxane T=25°C; Inert atmosphere;
参考文献
THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA
Patent: WO2009/137322 A2, 2009 ;
Location in patent: Page/Page column 21; 22; 29; 30; 31 ;
905966-40-7
+
38262-42-9
→
反应条件
229467-26-9
4-(萘-1-基)苯甲酸甲酯
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 12 h; Inert atmosphere;
参考文献
Leowanawat, Pawaret; Zhang, Na; Percec, Virgil
Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 1018 - 1025
905966-40-7
+
1144-13-4
→
反应条件
229467-26-9
4-(萘-1-基)苯甲酸甲酯
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 12 h; Inert atmosphere;
参考文献
Leowanawat, Pawaret; Zhang, Na; Percec, Virgil
Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 1018 - 1025
905966-40-7
→
反应条件
229467-26-9
4-(萘-1-基)苯甲酸甲酯
反应条件
bis(1,5-cyclooctadiene)nickel (0); cesium fluoride; tri-cyclo-hexyl-phosphine in toluene T=120°C; 19 h;
参考文献
Leowanawat, Pawaret; Zhang, Na; Percec, Virgil
Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 1018 - 1025
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