3-甲氧基-5-(4,4,5,5-四甲基-1,3,2-二噁硼烷-2-基)苯酚合成路线 (共 3 条)
反应条件
potassium acetate; tri-cyclo-hexyl-phosphine; tris-(dibenzylideneacetone)dipalladium(0) in ethylene glycol dimethyl ether
T=150°C; 2 h; Microwave;
参考文献
ASTRAZENECA AB; ASTEX THERAPEUTICS LTD
Patent: WO2007/58602 A2, 2007 ;
Location in patent: Page/Page column 126-127 ;
WO 2007/058602 A2
反应条件
bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 4,4'-di-tert-butyl-2,2'-dipyridyl
T=80°C; 21 h;
参考文献
Ishikawa, Shunpei; Manabe, Kei
Chemical Communications, 2006 , # 24 p. 2589 - 2591
反应条件
caesium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in ethylene glycol dimethyl ether; ethanol; water
T=150°C; 0.666667 h; Microwave;
参考文献
ASTRAZENECA AB; ASTEX THERAPEUTICS LTD
Patent: WO2007/58602 A2, 2007 ;
Location in patent: Page/Page column 127 ;
WO 2007/058602 A2