1-碘-2,6-二甲基-4-甲氧基苯合成路线 （共 6 条）
反应条件
n-butyllithium; hexane 1.) Et2O, reflux, 2.5 h, 2.) hexane, Et2O, -10 deg C, 0.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brown, Roger F. C.; Eastwood, Frank W.; Horvath, Julianna
Australian Journal of Chemistry, 1995 , vol. 48, # 5 p. 1055 - 1058
反应条件
1: Et3N / Pd(OAc)2, tri-o-tolylphosphine / acetonitrile / Heating 2: H2 / <Rh(1,5-COD)(R,R-DIPAMP)>BF4 / ethyl acetate / 60 °C 3: 48percent HBr / Heating View Scheme
参考文献
Dygos; Yonan; Scaros; Goodmonson; Getman; Periana; Beck
Synthesis, 1992 , # 8 p. 741 - 743
反应条件
n-butyllithium; hexane 1.) Et2O, reflux, 2.5 h, 2.) hexane, Et2O, -10 deg C, 0.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brown, Roger F. C.; Eastwood, Frank W.; Horvath, Julianna
Australian Journal of Chemistry, 1995 , vol. 48, # 5 p. 1055 - 1058
反应条件
potassium hydroxide in dimethyl sulfoxide
T=25°C; 2 h;
参考文献
Moorthy, Jarugu Narasimha; Singhal, Nidhi; Senapati, Kalyan
Tetrahedron Letters, 2008 , vol. 49, # 1 p. 80 - 84
反应条件
1: KIO3; iodine; aqueous KOH / anschliessendes Ansaeuern
2: aqueous NaOH
View Scheme
参考文献
Goldschmidt; Suchanek
Chemische Berichte, 1957 , vol. 90, p. 19,25
参考文献
Goldschmidt; Suchanek
Chemische Berichte, 1957 , vol. 90, p. 19,25
