908093-98-1合成路线 (共 442 条)
反应条件
Cu(CH3CN(C6H3(CH3)2)CHCCH3N(C6H3(CH3)2))(CH2CH2) in toluene T=20°C; 26 h; Product distribution / selectivity;
参考文献
WO2005/7659 A2, ;
Page/Page column 42; 15 ;
反应条件
1: (7R)-7-aminocephalosporanic acid With sodium hydroxide; water 0.5 h; 2: glutaric acid anhydride in water 1.5 h; 3: diphenyldiazo-methane With hydrogenchloride in tetrahydrofuran; water pH=4.0 - 4.5; 30 h;
参考文献
WO2005/70457 A1, ;
Page/Page column 53; 61 ;
反应条件
in benzene T=65°C; 24 h;
参考文献
Tetrahedron, , vol. 43, # 8 p. 1793 - 1798
反应条件
in toluene T=20°C; 0.25 h; Reactivity;
参考文献
WO2005/7659 A2, ;
Page/Page column 44 ;
反应条件
copper acetylacetonate in benzene nitrogen atmosphere, 1.) reflux, 4-6h, 2.) room temperature, overnight;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 57, # 6 p. 1667 - 1670
反应条件
1: (S)-2-(3,4-Dimethoxy-phenyl)-8-(1,3-diphenyl-propyl)-5,7-dimethoxy-chroman With ruthenium trichloride; sodium periodate in tetrachloromethane; water; acetonitrile T=20°C; Oxidation; 2 h; 2: diphenyldiazo-methane in tetrahydrofuran; methanol T=20°C; Alkylation; 19.1 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 65, # 17 p. 5371 - 5381
反应条件
2,2,2-trifluoroethanol; tetra-n-butylammonium perchlorate in N,N-dimethyl-formamide Ambient temperatureelectrolytic reduction; other reagents, reagent ratio, potentials; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 102, # 27 p. 7867 - 7872
反应条件
tin(ll) chloride in ethylene glycol dimethyl ether T=17°C; 18 h; further diaryldiazoalkanes; stereoselectivity;
参考文献
Carbohydrate Research, , vol. 103, p. 41 - 52
反应条件
[Co(.eta.6-toluene)(Me2C6H3NC(Me)CHC(Me)NC6H3Me2)] in toluene T=20°C; 20 h; Product distribution / selectivity;
参考文献
WO2005/7659 A2, ;
Page/Page column 56 ;
反应条件
in benzene 18 h; Heating;
参考文献
Carbohydrate Research, , vol. 103, p. 41 - 52