hydrogen; palladium on activated charcoal in tetrahydrofuran T=20°C; P=2068.59 Torr; 22 h;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1903730', constants.ctx, '0')">trimethylsilylazide</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '3903215', constants.ctx, '0')">tin(IV) chloride</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1730800', constants.ctx, '0')">dichloromethane</a> <br />12&nbsp;h;&nbsp;&nbsp;Heating;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: bromine; iron / 1,1,2-trichloro-1,2,2-trifluoro-ethane / 3 h / 20 &deg;C<br />2: 74 percent / azidotrimethylsilane; SnCl₄ / CH₂Cl₂ / 12 h / Heating<br /> <br /> &nbsp;