1,8-diazabicyclo{5.4.0}undec-7-ene in 2-methoxy-ethanol a mixt. of the Cu salt, phthalonitrile, and the base (molar ratio 3:10:10) was refluxed in 2-methyl-cellosolve for 6 h;; the ppt. was filtered off, washed with 3percent HCl soln., water, and ethanol and purified by extrn. with CHCl3; IR, UV, XRD, and elem.anal.;;
1 equiv of NiCl2*2H2O, 4 equiv of oxime, 4 equiv of phthalonitrile, 100°C, 8 h;
参考文献
Kopylovich, Maximilian N.; Kukushkin, Vadim Yu.; Haukka, Matti; Luzyanin, Konstantin V.; Pombeiro, Armando J. L.
Journal of the American Chemical Society, 2004 , vol. 126, # 46 p. 15040 - 15041
1 equiv of NiCl2*2H2O, 4 equiv of oxime, 4 equiv of phthalonitrile, 100°C, 8 h;
参考文献
Kopylovich, Maximilian N.; Kukushkin, Vadim Yu.; Haukka, Matti; Luzyanin, Konstantin V.; Pombeiro, Armando J. L.
Journal of the American Chemical Society, 2004 , vol. 126, # 46 p. 15040 - 15041
in neat (no solvent) mixt. of Ni salt and phthalonitrile was heated at 453-458 K; dild. with concd. H2SO4; filtered; washed (H2O); dried at 373-383 K; elem. anal.;
参考文献
Tverdova, Natalya V.; Pimenov, Oleg A.; Girichev, Georgiy V.; Shlykov, Sergey A.; Giricheva, Nina I.; Mayzlish, Vladimir E.; Koifman, Oscar I.
Journal of Molecular Structure, 2012 , vol. 1023, p. 227 - 233
in not given byproducts: CO; template synthesis in NaY zeolite, catalytic activity described; dehydration of zeolite in vac., sorption of Ni(CO)4; sorption of phthalonitrile; holding at 70.degre.C for 8-10 h; raising to 100-120.dergree.C;; washing with acetone for several h, extraction of surface complex with DMF, extraction of topologically bound complex with H2SO4; identification by UV spectroscopy in both extracts;;
参考文献
Zakharov, A. N.
Kinetics and Catalysis, 1991 , vol. 32, p. 1230 - 1236
Kinetika i Kataliz, 1991 , vol. 32, p. 1377 - 1384
