in further solvent(s) Heating of anhyd. metal salt with phthalonitrile in the presence of urea in 1-chloronaphthalene for 5 h at 175-180°C (ammonium molybdateas catalyst).; Successive boiling with aq. HCl and aq. NH4OH, extg. (hot MeOH).;
参考文献
Berlin, Yu. A.; Danielyan, N. G.; Beshenko, S. I.; Zhorin, V. A.; Enikolopyan, N. S.
Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk), 1986 , vol. 286 - 288, p. 34 - 37
Doklady Akademii Nauk SSSR, 1986 , vol. 286, p. 364 - 367
sodium methylate in acetonitrile Sonication; Cd added to a CH3CN soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30percent soln of CH3ONa in methanol; flask put into an ultrasonic cleaner and maintained at 50°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97percent; elem. anal.;
参考文献
Kharisov; Ortiz Mendez; Rivera De La Rosa
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2006 , vol. 32, # 9 p. 617 - 631
1,8-diazabicyclo{5.4.0}undec-7-ene in cellosolve=2-ethoxyethanol a mixt. of the Cu salt, phthalonitrile, and the base (molar ratio 3:10:10) was refluxed in ethyl-cellosolve for 6 h;; the ppt. was filtered off, washed with water and ethanol, and purified by extrn. with CHCl3; IR, UV, XRD, and elem.anal.;;
