tert.-butylhydroperoxide in decane; acetonitrile T=70°C; 8.5 h; Catalytic behavior; regioselective reaction;

KBrO3; V(IV) in sulfuric acid; acetic acid T=30°C; Rate constant;

perchloric acid; phenyliodosyl acetate in water T=35°C; ΔH(excit.), ΔS(excit.), E(activ.), also in the presence of HOAc, acrylonitrile, NaClO4, NaOAc, Cl(-), I(-), Br(-); Rate constantThermodynamic dataMechanism;

hexacyanoruthenate(III); sodium perchlorate in perchloric acid; water T=25°C; ΔH(excit.), ΔS(excit.); Rate constantThermodynamic data;

lt;Rh2(O2CCh3)4(OH2)2gt;(1+) in perchloric acid T=25°C; ΔHact, ΔSact, varied: ionic stength, <H+>; Equilibrium constantThermodynamic dataMechanism;