2,6-二氯-4-甲基吡啶-3-羧醛合成路线 （共 5 条）
反应条件
sodium chlorite; sodium dihydrogenphosphate in water; tert-butyl alcohol T=10 - 25°C; Oxidation; 4 h;
参考文献
Sarkar, Tarun K.; Ghosh, Sunil K.; Chow, Tahsin J.
Journal of Organic Chemistry, 2000 , vol. 65, # 10 p. 3111 - 3115
反应条件
Cyclization; electrocyclization; UV-irradiation;
参考文献
Tetrahedron Letters, , vol. 41, # 35 p. 6909 - 6913
反应条件
diisobutylaluminium hydride in dichloromethane; toluene
T=-78 - 20°C; Reduction; 2 h;
参考文献
Sarkar, Tarun K.; Ghosh, Sunil K.; Chow, Tahsin J.
Journal of Organic Chemistry, 2000 , vol. 65, # 10 p. 3111 - 3115
反应条件
pyridinium chlorochromate in dichloromethane
T=20°C; 6 h;
参考文献
Li, Xiangmin; Wang, Sinan; Li, Tengfei; Li, Jian; Li, Hao; Wang, Wei
Organic Letters, 2013 , vol. 15, # 22 p. 5634 - 5637
反应条件
1: borane-THF / tetrahydrofuran / 6 h / 20 °C / |Inert atmosphere
2: pyridinium chlorochromate / dichloromethane / 6 h / 20 °C
View Scheme
参考文献
Li, Xiangmin; Wang, Sinan; Li, Tengfei; Li, Jian; Li, Hao; Wang, Wei
Organic Letters, 2013 , vol. 15, # 22 p. 5634 - 5637
