反应条件
Stage #1: <a href="#" onclick="return RXDsubstances(event, this, '906752', constants.ctx, '0')">trimethylsilylacetylene</a> <b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '1209227', constants.ctx, '0')">n-butyllithium</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a>; <a href="#" onclick="return RXDsubstances(event, this, '1730733', constants.ctx, '0')">hexane</a> <br />T=-78°C; 1 h; Inert atmosphere; <br />Stage #2: <a href="#" onclick="return RXDsubstances(event, this, '1209245', constants.ctx, '0')">1,5-Dibromopentane</a> <b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '1099903', constants.ctx, '0')">tris(dimethylamino)phosphine oxide</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a>; <a href="#" onclick="return RXDsubstances(event, this, '1730733', constants.ctx, '0')">hexane</a> <br />T=-78 - 20°C; 16 h; Inert atmosphere; <br />
参考文献
Fer, Mickal J.; Bouhss, Ahmed; Patro, Mariana; Le Corre, Laurent; Pietrancosta, Nicolas; Amoroso, Ana; Joris, Bernard; Mengin-Lecreulx, Dominique; Calvet-Vitale, Sandrine; Gravier-Pelletier, Christine Organic and Biomolecular Chemistry, 2015 , vol. 13, # 26 p. 7193 - 7222
