1: ([1-(2-bromophenyl)ethoxy]diphenylsilyl)trimethylgermane With azobisisobutyronitrile; tri-n-butyl-tin hydride in benzene
Rearrangement; 7.5 h;
2: methyllithium in benzene
T=20°C; Ring cleavage; desilylation; 12 h; Further stages. Title compound not separated from byproducts.;
1: [1-(2-bromophenyl)ethoxy]diphenylmethylsilane With azobisisobutyronitrile; tri-n-butyl-tin hydride in benzene
Rearrangement; 7.5 h;
2: methyllithium in benzene
desilylation; Further stages.;
copper(l) iodide; methyl iodide
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Khrimyan, A. P.; Garibyan, O. A.; Panosyan, G. A.; Mailyan, N. Sh.; Kinoyan, F. S.; et al.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 12 p. 1961 - 1973
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 12 p. 2351 - 2365
