in diethyl ether
(N2); dropwise addn. (1 h) of a soln. of methyllithium into the soln. of GeCl3CH2Cl at -70 °C under vigorous stirring; addnl. stirring (1.5 h); then standing the mixt. until room temp. was reached and addnl. stirring for 16 h;; filtration; then distg. the solvent off from the filtrate; vacuum distn.;
参考文献
Tacke, Reinhold; Becker, Beate
Journal of Organometallic Chemistry, 1988 , vol. 354, p. 147 - 154
in tetrahydrofuran
T=-78 - 23°C; other lithiated nucleophiles; Product distribution;
参考文献
Griera, Rosa; Rigat, Lluis; Alvarez, Mercedes; Joule, John A.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 10 p. 1223 - 1228
