N,N,N',N,-tetramethylethylenediamine
1) ether, -55 deg C, 0.08 h, 2) -55 deg C to rt; Yield given. Multistep reaction;
参考文献
Seijas, Julio A.; Vazquez-Tato, M. Pilar; Castedo, Luis; Estevez, Ramon J.; Ruiz, Maria
Journal of Organic Chemistry, 1992 , vol. 57, # 20 p. 5283 - 5284
Okazaki, Renji; Tokitoh, Norihiro; Ishii, Akihiko; Ishii, Naoko; Matsuhashi, Yasusuke; et al.
Phosphorus, Sulfur and Silicon and the Related Elements, 1992 , vol. 67, # 1-4 p. 49 - 66
Gulliver, David J.; Hope, Eric G.; Levason, William; Murray,Stephen G.; Potter, David M.; Marshall, Gregory L.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , # 3 p. 429 - 434
in tetrahydrofuran; diethyl ether
under Ar; adding dropwise a soln. of CH3Li in Et2O to a soln. of MoCl5 in THF (3 mol CH3Li/mol MoCl5, -70°C, 1 drop/7 - 10 s), standing (2 - 4 h, -70°C);
