carbon dioxide in diethyl ether; water react. of (C6F5)3SiH with CH3Li at -50°C, 1 h gives after treatment of the react. product with CO2 in H2O/H(1+) C6F5COOH;
1: With (Sa)-2'-[(R)-hydroxy(phenyl)methyl]-(1,1'-binaphthalen)-2-ol; titanium (IV) isopropoxide in toluene T=-40°C; 1 h; Inert atmosphere; 2: With hydrogenchloride in water Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Fernandez-Mateos, Emilio; MacIa, Beatriz; Yus, Miguel
European Journal of Organic Chemistry, 2012 , # 20 p. 3732 - 3736
