in diethyl ether; hexane byproducts: LiCl; all manipulations carried out under dry Ar; soln. of LiMe in diethyl ether slowly added to an ice-cold suspension of Ti-compd. in hexane, mixt. left to reach room temp. with stirring for 4h; filtered, evapd., recrystn. (pentane, -78°C); elem. anal.;
参考文献
Mena, Miguel; Royo, Pascual; Serrano, Ricardo; Pellinghelli, Maria Angela; Tiripicchio, Antonio
Organometallics, 1989 , vol. 8, p. 476 - 482
in tetrahydrofuran byproducts: Ru3(CO)12; from Ru3(μ3-NPh)(CO)10 and MeLi in THF to the intermediate cluster, addn. of excess HBF4 at -78°C, warming to room temp.; removing of solvent (vac.), chromy. (silica gel, hexane): isolation as second band;
Gulliver, David J.; Hope, Eric G.; Levason, William; Murray,Stephen G.; Potter, David M.; Marshall, Gregory L.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , # 3 p. 429 - 434
