1: 1-bromo-4-[2-(diphenylphophinothioyl)ethylsulfanyl]benzene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.5 h;
2: N,N-dimethyl-formamide in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Oliveri, Christopher G.; Gianneschi, Nathan C.; Nguyen, SonBinh T.; Mirkin, Chad A.; Stern, Charlotte L.; Wawrzak, Zdzislaw; Pink, Maren
Journal of the American Chemical Society, 2006 , vol. 128, # 50 p. 16286 - 16296
1.1: Cs2CO3 / acetonitrile / Heating
2.1: 92 percent / S8 / tetrahydrofuran / 3 h
3.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C
3.2: 88 percent / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
参考文献
Oliveri, Christopher G.; Gianneschi, Nathan C.; Nguyen, SonBinh T.; Mirkin, Chad A.; Stern, Charlotte L.; Wawrzak, Zdzislaw; Pink, Maren
Journal of the American Chemical Society, 2006 , vol. 128, # 50 p. 16286 - 16296
1.1: Cs2CO3 / acetonitrile / Heating
2.1: 92 percent / S8 / tetrahydrofuran / 3 h
3.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C
3.2: 88 percent / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
参考文献
Oliveri, Christopher G.; Gianneschi, Nathan C.; Nguyen, SonBinh T.; Mirkin, Chad A.; Stern, Charlotte L.; Wawrzak, Zdzislaw; Pink, Maren
Journal of the American Chemical Society, 2006 , vol. 128, # 50 p. 16286 - 16296
1.1: 92 percent / S8 / tetrahydrofuran / 3 h
2.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C
2.2: 88 percent / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
参考文献
Oliveri, Christopher G.; Gianneschi, Nathan C.; Nguyen, SonBinh T.; Mirkin, Chad A.; Stern, Charlotte L.; Wawrzak, Zdzislaw; Pink, Maren
Journal of the American Chemical Society, 2006 , vol. 128, # 50 p. 16286 - 16296
