2-甲基-1-戊烯-3-炔合成路线 （共 34 条）
反应条件
in benzene-d6
byproducts: CH4; Sc-compd., propyne, and benzene-d6 sealed in a NMR tube at room temp. for 0.5 h; not isolated, detected by NMR;
参考文献
Thompson,M.E.; Baxter,S.M.; Bulls,A.R.
Journal of the American Chemical Society, 1987 , vol. 109, p. 203
反应条件
1: liq. NH3, NaNH2
2: (CF3CO)2O, EtN(iPr)2 / CH2Cl2 / 1) -78 deg C, 2) -40 deg C, 30 min
View Scheme
参考文献
Hoffmann, H. M. R.; Matthei, Juergen
Chemische Berichte, 1980 , vol. 113, # 12 p. 3837 - 3847
反应条件
1,1-bis-(p-chlorophenyl)-ethanol
T=110°C; 42 h; Further byproducts given;
参考文献
Deohring, A.; Jolly, P. W.
Tetrahedron Letters, 1980 , vol. 21, p. 3021 - 3024
参考文献
Kupin; Petrow
Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 3738,3741;engl.Ausg.S.3695,3698
反应条件
hydrogenchloride
Heating;
参考文献
Easton,N.R. et al.
Journal of Organic Chemistry, 1965 , vol. 30, p. 3084 - 3088
反应条件
in pentane
72 h; Irradiation; Further byproducts given;
参考文献
Rudolph, Andreas; Margaretha, Paul; Agosta, William C.
Helvetica Chimica Acta, 1987 , vol. 70, p. 339 - 341
反应条件
Rh2Cl2(N-allylaniline)3 in benzene
T=20°C; P=760 Torr; other unsaturated organic compounds, var. concentration of catalyst, var. solvents, var. temp.; other catalyst; Product distribution;
参考文献
Aresta, M.; Fazio, M. De
Journal of Organometallic Chemistry, 1980 , vol. 186, # 1 p. 109 - 120
反应条件
in benzene
a soln. of Y-complex in benzene was exposed to a large excess of propyne at room temp. for 3 h; org. product and solvent were distilled off (sepd. by distillation), residue was examined by IR and (1)H NMR spectroscopy;
参考文献
Haan, Klaas H. den; Wielstra, Ytsen; Teuben, Jan H.
Organometallics, 1987 , vol. 6, p. 2053 - 2060
反应条件
formaldehyd; bis(acetylacetonato) palladium; triethylaluminum; triphenylphosphine in toluene
T=100°C; 6 h; Product distribution;
参考文献
Selimov, F. A.; Rutman, O. G.; Dzhemilev, U. M.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1621 - 1624
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 9 p. 1853 - 1856
反应条件
cis-lt;Rh(diphos)(CO)2gt;lt;BPh4gt; in acetonitrile
T=120°C; P=45600 Torr; 12 h; also without CO2; also dienes;
参考文献
Albano, P.; Aresta, M.
Journal of Organometallic Chemistry, 1980 , vol. 190, # 3 p. 243 - 246
