反应条件
1.1: 88 percent / NaH / dimethylformamide; various solvent(s) / 0 - 20 °C
2.1: n-BuLi / hexane; tetrahydrofuran / 0.33 h / -78 °C
2.2: 85 percent / tetrahydrofuran; hexane / -78 - 20 °C
3.1: ozone / -78 °C
3.2: 80 percent / pyridine / CH2Cl2 / -78 - 20 °C
4.1: H2 / 10 percent Pt/C / methanol / 72 h / 2585.74 Torr
4.2: H2 / 10 percent Pd/C / methanol / 96 h / 2585.74 Torr
View Scheme
参考文献
Ahmed, Aqeel; Crawford, Terry; Gould, Stephanie; Ha; Hollrah, Monica; Noor-E-Ain, Farhana; Dickman, Martin B.; Dussault, Patrick H.
Phytochemistry, 2003 , vol. 63, # 1 p. 47 - 52
