1,8-二氨基-3,6-二氧杂辛烷合成路线 （共 65 条）
反应条件
2: LiAlH4 3: Et3N 4: B2H6 5: (i) aq. HCl, (ii) ion-exchange resin <OH- form> View Scheme
参考文献
Dietrich,B. et al.
Tetrahedron, 1973 , vol. 29, p. 1629 - 1645
反应条件
in methanol P=6000480 Torr; 48 h; Ambient temperature;
参考文献
Gluzinski, P.; Krajewski, J. W.; Kasprzyk, S.; Salanski, P.; Stankiewicz, T.; Jurczak, J.
Journal of Crystallographic and Spectroscopic Research, 1992 , vol. 22, # 1 p. 15 - 19
反应条件
1: benzene / Heating 2: benzene / 1 h / Heating 3: aq.H2SO4 / 1 h / Heating View Scheme
参考文献
Bogat-skii, A.V.; Luk'yanenko, N.G.; Shapkin, V.A.; Popkov, Yu.A.; Nazarova, N.Yu.; Chernotkach, Z.A.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, p. 798 - 804
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 4 p. 878 - 885
参考文献
Geigy A.G.
Patent: US2709178 , 1951 ;
反应条件
1: With KClO4 in methanol T=20°C; 48 h; 2: With sodium tetrahydroborate in methanol T=5°C; Further stages;
参考文献
Tetrahedron, , vol. 66, # 49 p. 9532 - 9537
反应条件
1: With KClO4 in methanol T=20°C; 48 h; 2: With sodium tetrahydroborate in methanol T=5°C; Further stages;
参考文献
Tetrahedron, , vol. 66, # 49 p. 9532 - 9537
反应条件
1: benzene-1,3-dicarbaldehyde; 2-[2-(2-aminoethoxy)ethoxy]-ethylamine With KClO4 in methanol T=20°C; 48 h; 2: With sodium tetrahydroborate in methanol T=5°C; 3: methyl chloroformate Further stages;
参考文献
Tetrahedron, , vol. 66, # 49 p. 9532 - 9537
反应条件
1: benzene-1,3-dicarbaldehyde; 2-[2-(2-aminoethoxy)ethoxy]-ethylamine With ammonium perchlorate in methanol T=20°C; 48 h; 2: With sodium tetrahydroborate in methanol T=5°C; 3: methyl chloroformate Further stages;
参考文献
Tetrahedron, , vol. 66, # 49 p. 9532 - 9537
反应条件
1: benzene-1,3-dicarbaldehyde; 2-[2-(2-aminoethoxy)ethoxy]-ethylamine With KClO4 in methanol T=20°C; 48 h; 2: With sodium tetrahydroborate in methanol T=5°C; 3: methyl chloroformate Further stages;
参考文献
Tetrahedron, , vol. 66, # 49 p. 9532 - 9537
反应条件
lithium perchlorate in acetonitrile T=80°C; 24 h; Inert atmosphere;
参考文献
Huczynski, Adam; Ratajczak-Sitarz, Malgorzata; Katrusiak, Andrzej; Brzezinski, Bogumil
Journal of Molecular Structure, 2009 , vol. 930, # 1-3 p. 26 - 31
