trichlorophosphate

1: phosphoryl chloride 2: hydrochloric acid; water View Scheme

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '19252662', constants.ctx, '0')">1-methyl-cyclohexanol-⁽⁴⁾</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '4122947', constants.ctx, '0')">copper</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '4154566', constants.ctx, '0')">sodium carbonate</a> <br /> <br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11405916', constants.ctx, '0')">copper(l) iodide</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '4267587', constants.ctx, '0')">potassium carbonate</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '605365', constants.ctx, '0')">N,N-dimethyl-formamide</a> <br />T=120&deg;C;&nbsp;Ullmann Condensation;&nbsp;4&nbsp;h;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 4 steps<br /> </b>1: dichloromethane / 1 h / 20 &deg;C<br />2: nitric acid; acetic acid / 0.5 h / 0 &deg;C<br />3: hydrogenchloride / water / 2 h / |Reflux<br />4: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 4 h / 120 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 5 steps<br /> </b>1: nitric acid; sulfuric acid / 2 h / 70 &deg;C<br />2: potassium permanganate; water / 8 h / |Reflux<br />3: palladium 10 on activated carbon / tetrahydrofuran / 24 h / 20 &deg;C<br />4: sodium nitrite; hydrogenchloride; potassium iodide / dichloromethane / 4 h / 0 - 20 &deg;C<br />5: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 4 h / 120 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 4 steps<br /> </b>1: potassium permanganate; water / 8 h / |Reflux<br />2: palladium 10 on activated carbon / tetrahydrofuran / 24 h / 20 &deg;C<br />3: sodium nitrite; hydrogenchloride; potassium iodide / dichloromethane / 4 h / 0 - 20 &deg;C<br />4: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 4 h / 120 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: sodium nitrite; hydrogenchloride; potassium iodide / dichloromethane / 4 h / 0 - 20 &deg;C<br />2: potassium carbonate; copper(l) iodide / N,N-dimethyl-formamide / 4 h / 120 &deg;C<br /> <br /> &nbsp;