3,4-环氧-1-丁烯合成路线 (共 241 条)
反应条件
hydrogen in ethanol T=30°C; P=4500.45 Torr; Reagent/catalystSolventTemperature;
参考文献
Kahsar, Karl R.; Schwartz, Daniel K.; Medlin, J. Will
Applied Catalysis A: General, 2012 , vol. 445-446, p. 102 - 106
反应条件
hydrogen; silica gel; palladium T=-0.15°C; P=150.012 Torr; also ethyloxirane; also with duterium; also over Pt-SiO2; var. temp. and time; Product distributionMechanism;
参考文献
Bartok, Mihaly; Fasi, Andras; Notheisz, Ferenc
Journal of Catalysis, 1998 , vol. 175, # 1 p. 40 - 47
反应条件
hydrogen; lt;Rh(NBD)(PPh3)2gt;lt;ClO4gt; T=30°C; P=760 Torr; 8 h; catalytic hydrogenation of the title compound in the presence of various catalysts (cationic rhodium complexes); influence of the type of catalyst's ligand, reaction time and pressure on the activity of catalysts; Product distributionMechanism;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 855 - 860
反应条件
hydrogen; Ag-Pt/SiO2 KineticsProduct distribution; Further Variations:Catalystseffect of Ag addition;
参考文献
Schaal, Melanie T.; Pickerell, Anna C.; Williams, Christopher T.; Monnier, John R.
Journal of Catalysis, 2008 , vol. 254, # 1 p. 131 - 143
反应条件
1: Butadiene monooxide With 3,3-dimethyldioxirane in acetone T=-15°C; 2.5 h; 2: L-2'-deoxyguanosine in acetic acid T=60°C; 22 h; 3: With hydrogenchloride T=80°C; 2.5 h;
参考文献
Oe, Tomoyuki; Kambouris, Sara J.; Walker, Vernon E.; Meng, Quanxin; Recio, Leslie; Wherli, Suzanne; Chaudhary, Ajai K.; Blair, Ian A.
Chemical Research in Toxicology, 1999 , vol. 12, # 3 p. 247 - 257
反应条件
hydrogen; lt;Rh(NBD)(PPh3)2gt;lt;ClO4gt; T=30°C; P=760 Torr; 8 h; catalytic hydrogenation of the title compound in the presence of various catalysts (cationic rhodium complexes); influence of the type of catalyst's ligand, reaction time and pressure on the activity of catalysts; Product distributionMechanism;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 855 - 860
参考文献
Aisikowitsch et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 3046,3050; engl. Ausg. S. 3076, 3079
参考文献
Aisikowitsch et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 3046,3050; engl. Ausg. S. 3076, 3079
反应条件
1: Butadiene monooxide With 3,3-dimethyldioxirane in acetone T=-15°C; 2.5 h; 2: L-2'-deoxyguanosine in acetic acid T=60°C; 22 h; 3: With hydrogenchloride T=80°C; 2.5 h;
参考文献
Oe, Tomoyuki; Kambouris, Sara J.; Walker, Vernon E.; Meng, Quanxin; Recio, Leslie; Wherli, Suzanne; Chaudhary, Ajai K.; Blair, Ian A.
Chemical Research in Toxicology, 1999 , vol. 12, # 3 p. 247 - 257
参考文献
Chevron Research Company
Patent: US3932468 A1, 1976 ;