1: monochlorocyclopentane With magnesium in tetrahydrofuran 1 h; RefluxInert atmosphere; 2: water-d2 in tetrahydrofuran T=0°C; Inert atmosphere;
参考文献
Duckett, Simon B.; George, Michael W.; Jina, Omar S.; Matthews, Steven L.; Perutz, Robin N.; Sun, Xue-Zhong; Vuong, Khuong Q.
Chemical Communications, 2009 , # 11 p. 1401 - 1403
fluorine
T=-30 - 10°C; Irradiationsteady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation; Further byproducts given. Yields of byproduct given;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
fluorine
T=-30 - 10°C; Irradiationsteady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation; MechanismProduct distribution;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
fluorine
T=-30 - 10°C; Irradiationsteady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation; Further byproducts given. Yields of byproduct given;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
