1: 3-(butyltellanyl)propan-1-ol With n-butyllithium in tetrahydrofuran; hexane
cooling;
2: in tetrahydrofuran; hexane
T=-70°C; 1 h;
3: cyclohexenon in tetrahydrofuran; hexane
T=-78 - 20°C; Further stages.;
参考文献
Dos Santos, Alcindo A.; Princival, Jefferson L.; Comasseto, Joao V.; de Barros, Simone M.G.; Neto, Jose E. Brainer
Tetrahedron, 2007 , vol. 63, # 24 p. 5167 - 5172
1: 3-chloropropan-1-ol With methyl-magnesium chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: With magnesium; ethylene dibromide in tetrahydrofuran
1 h; Heating;
3: cyclohexenon With copper(I) bromide in tetrahydrofuran
T=-78 - 0°C; 1 h;
参考文献
Seo, Jai Woong; Comninos, John S.; Chi, Dae Yoon; Kim, Dong Wook; Carlson, Kathryn E.; Katzenellenbogen, John A.
Journal of Medicinal Chemistry, 2006 , vol. 49, # 8 p. 2496 - 2511
