反应条件
1: n-amyl iodide With chloro-trimethyl-silane; ethylene dibromide; zinc in tetrahydrofuran
T=35 - 40°C; Metallation; 12 h;
2: With copper diacetate; lithium chloride in tetrahydrofuran
T=-18°C; transmetalation; 0.166667 h;
3: cyclohexenon With chloro-trimethyl-silane in tetrahydrofuran; diethyl ether
T=-18 - -10°C; Addition; 1 h;
参考文献
Hu, Yulai; Yu, Jianhua; Yang, Shiyan; Wang, Jin-Xian; Yin, Yuanqi
Synthetic Communications, 1998 , vol. 28, # 15 p. 2793 - 2800
