2,2'-二吡啶-6,6'-二胺合成路线 （共 20 条）
反应条件
ammonia; KNH2; iron nitrate (III) in toluene T=-33°C; 4 h;
参考文献
Thibault, Michelle E.; Luska, Kylie L.; Schlaf, Marcel
Synthesis, 2007 , # 5 p. 791 - 793
反应条件
tributylphosphine in methanol; water T=20°C; 5 h;
参考文献
Shimada, Hiroshi; Sakurai, Toshihiko; Kitamura, Yusuke; Matsuura, Hirotaka; Ihara, Toshihiro
Dalton Transactions, 2013 , vol. 42, # 45 p. 16006 - 16013
反应条件
1.1: BuLi; Cu 1.2: O2 2.1: 95 percent / potassium amide; ammonia / iron(III) nitrate nonahydrate / toluene / 4 h / -33 °C View Scheme
参考文献
Synthesis, , # 5 p. 791 - 793
反应条件
1: 90 percent / NaNO2; conc. HCl / H2O / 6 h / 0 - 20 °C 2: 83 percent / tri-n-butylphosphine / methanol; H2O / 5 h / 20 °C View Scheme
参考文献
Heterocycles, , vol. 65, # 2 p. 293 - 301
反应条件
1-iso-propyl-4-methylbenzene; sodium amide T=150 - 160°C;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 54, p. 275,281
反应条件
ammonium tetrachlorozincate T=320 - 330°C;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2527 - 2530
反应条件
heated under N2 at 320-330°C for 6 h; starting material removed by sublimation, washed (H2O), treated with 10percent NaOH, washed (H2O), sublimation (200°C/0.5 mmHg, 3 h) for organic product, residue dissolved in 5percent aq. AcOH, pptd. (NaOH), recrystd. (AcOH), elem. anal.;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2527 - 2530
反应条件
1: 99 percent / PCl5, phosphoryl chloride / 20 h / Heating 2: 6 percent / ammonium tetrachlorozincate / 320 - 330 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2527 - 2530
反应条件
1: copper-powder; biphenyl 2: bromine / 500 °C 3: water; NH3 / 220 °C View Scheme
参考文献
Journal of the Chemical Society, , p. 1662,1669
反应条件
copper dichloride in water T=20°C; pH 7.2; var. MeOH/H2O percent v/v; Rate constant;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 15 p. 1060 - 1062
