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乙二醇
甲醛
63148-62-9
MDI
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二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
93185-10-5
合成路线
(共 9 条)
93185-10-5
→
反应条件
134149-18-1
+
135482-22-3
+
41079-58-7
反应条件
copper diacetate; manganese triacetate in dimethyl sulfoxide T=75°C; 68 h;
参考文献
Snider, Barry B.; McCarthy, Bridget A.
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6217 - 6223
93185-10-5
→
反应条件
120790-39-8
+
134149-18-1
反应条件
Mn(OAc)3; copper diacetate in dimethyl sulfoxide T=80°C; 24 h;
参考文献
Powell, Luke H.; Docherty, Paul H.; Hulcoop, David G.; Kemmitt, Paul D.; Burton, Jonathan W.
Chemical Communications, 2008 , # 22 p. 2559 - 2561
93185-10-5
→
反应条件
120790-38-7
+
134149-18-1
+
135482-22-3
+
142836-50-8
反应条件
ammonium cerium(IV) nitrate in methanol T=20°C; 5 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Baciocchi; Paolobelli; Ruzziconi
Tetrahedron, 1992 , vol. 48, # 22 p. 4617 - 4622
93185-10-5
→
反应条件
120790-38-7
+
134149-18-1
+
135482-22-3
+
41079-58-7
反应条件
copper diacetate; manganese triacetate in N,N-dimethyl-formamide T=75°C; 67 h; other times, temperatures and solvents; Product distribution;
参考文献
Snider, Barry B.; McCarthy, Bridget A.
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6217 - 6223
93185-10-5
→
反应条件
120790-38-7
+
134149-18-1
+
135482-22-3
+
41079-58-7
+
142836-50-8
反应条件
ammonium cerium(IV) nitrate in methanol T=20°C; 5 h; various Cu-compounds as cooxidant; Product distribution;
参考文献
Baciocchi; Paolobelli; Ruzziconi
Tetrahedron, 1992 , vol. 48, # 22 p. 4617 - 4622
93185-10-5
→
反应条件
134149-18-1
+
135482-22-3
+
41079-58-7
+
142836-51-9
+
142836-50-8
反应条件
ammonium cerium(IV) nitrate in acetic acid T=20°C; 22 h; various Cu-compounds as cooxidant; Product distribution;
参考文献
Baciocchi; Paolobelli; Ruzziconi
Tetrahedron, 1992 , vol. 48, # 22 p. 4617 - 4622
93185-10-5
→
反应条件
120790-38-7
+
134149-18-1
反应条件
potassium tert-butylate; Pd(dppe) multistep reaction; conditions: diverse catalysts, different solvents, different temperatures; Product distributionMechanism;
参考文献
Monteiro, Nuno; Gore, Jacques; Balme, Genevieve
Tetrahedron, 1992 , vol. 48, # 46 p. 10103 - 10114
93185-10-5
→
反应条件
72963-31-6
反应条件
1: 1.) KH, 2.) N-iodosuccinimide (NIS) / 1.) -78 deg C 2: Me3SnH / 85 °C View Scheme
参考文献
Curran, Dennis P.; Chang, Chi-Tai
Journal of Organic Chemistry, 1989 , vol. 54, # 13 p. 3140 - 3157
93185-10-5
→
反应条件
4475-07-4
2-(4-戊烯)丙二酸
反应条件
ethanol; sodium hydroxide in water 16 h; Inert atmosphereReflux;
参考文献
Kochi, Takuya; Hamasaki, Taro; Aoyama, Yuka; Kawasaki, Junichi; Kakiuchi, Fumitoshi
Journal of the American Chemical Society, 2012 , vol. 134, # 40 p. 16544 - 16547,4