1: 2-(1-adamantyl)-4-bromo-1-methoxybenzene With magnesium; ethylene dibromide in tetrahydrofuran T=45 - 55°C; 1.5 h; 2: With zinc(II) chloride in tetrahydrofuran T=20 - 25°C; 1 h; 3: 6-bromo-naphthalene-2-carboxylic acid methyl ester With Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran T=20°C; 2 h;

1: 2-(1-adamantyl)-4-bromo-1-methoxybenzene With magnesium; ethylene dibromide in tetrahydrofuran T=35 - 45°C; 0.75 h; Heating / reflux; 2: With zinc(II) chloride in tetrahydrofuran T=22 - 38°C; 1 h; 3: 2-(1-adamantyl)-4-bromo-1-methoxybenzene With palladium diacetate in tetrahydrofuran 24 h; Heating / reflux;