4,4-二甲氧基-2,5-环己二烯-1-酮合成路线 （共 49 条）
反应条件
lithium perchlorate in acetonitrile
Electrochemical reaction;
参考文献
Deffieux, Denis; Fabre, Isabelle; Courseille, Christian; Quideau, Stephane
Journal of Organic Chemistry, 2002 , vol. 67, # 13 p. 4458 - 4465
反应条件
1: 77 percent / methanol / Ambient temperature; anodic oxidation, graphite felt anode, platinum cathode, one compartment cell, tetraethylammonium perchlorate
2: 95 percent / neutral alumina column / ethyl acetate
View Scheme
参考文献
Coutts, Ian G. C.; Culbert, Nicholas J.; Edwards, Mark; Hadfield, John A.; Musto, Donald R.; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1829 - 1836
反应条件
1: 100 percent / methanol / Ambient temperature; anodic oxidation, graphite felt anode, platinum cathode, one compartment cell, tetraethylammonium perchlorate
2: 98 percent / neutral alumina column / ethyl acetate
View Scheme
参考文献
Coutts, Ian G. C.; Culbert, Nicholas J.; Edwards, Mark; Hadfield, John A.; Musto, Donald R.; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1829 - 1836
反应条件
[bis(acetoxy)iodo]benzene
0.0833333 h; Ambient temperature; Title compound not separated from byproducts;
参考文献
Mitchell, Anthony S.; Russell, Richard A.
Tetrahedron, 1997 , vol. 53, # 12 p. 4387 - 4410
反应条件
1: 1) n-butyllithium / 1) THF, hexane, -78 deg C, 0.5 h, then 0 deg C, 1.5 h, 2) THF, -78 deg C, 4 h
2: aq. H2SO4 / 2 h / Heating
View Scheme
参考文献
Hart, David J.; Kim, Adrienne; Krishnamurthy, Ramanarayanan; Merriman, Gregory H.; Waltos, Anne-Marie
Tetrahedron, 1992 , vol. 48, # 38 p. 8179 - 8188
反应条件
trimethylsilyl trifluoromethanesulfonate; triethylamine in dichloromethane
19 h; Ambient temperature;
参考文献
Duthaler; Wegmann
Helvetica Chimica Acta, 1984 , vol. 67, # 7 p. 1755 - 1766
反应条件
1: 1) n-butyllithium / 1) THF, hexane, -78 deg C, 0.5 h, then 0 deg C, 1.5 h, 2) THF, -78 deg C, 4 h
2: aq. H2SO4 / 2 h / Heating
3: K2CO3 / acetone / 16 h / Heating
View Scheme
参考文献
Hart, David J.; Kim, Adrienne; Krishnamurthy, Ramanarayanan; Merriman, Gregory H.; Waltos, Anne-Marie
Tetrahedron, 1992 , vol. 48, # 38 p. 8179 - 8188
反应条件
pyridine in chloroform
T=90°C; 6 h; Inert atmosphere;
参考文献
Zhang, Jinzhu; Yin, Zhiwei; Leonard, Patrick; Wu, Jing; Sioson, Kate; Liu, Che; Lapo, Robert; Zheng, Shengping
Angewandte Chemie - International Edition, 2013 , vol. 52, # 6 p. 1753 - 1757
Angew. Chem., 2013 , vol. 125, # 6 p. 1797 - 1801,5
反应条件
pyridine; hydroxylamine hydrochloride
参考文献
Taylor,E.C. et al.
Journal of Organic Chemistry, 1978 , vol. 43, # 22 p. 4385 - 4387
反应条件
pyridine; boron trifluoride diethyl etherate
参考文献
Taylor,E.C. et al.
Journal of Organic Chemistry, 1978 , vol. 43, # 22 p. 4385 - 4387
