反应条件
1: 2,2-dimethyl-1-propanenitrile With 4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran
T=-78°C; 0.0916667 h; Inert atmosphere;
2: With C5H11CuNSi(1-)*Li(1+) in tetrahydrofuran; pentane
T=-78°C; 0.25 h; Inert atmosphere;
3: cyclohexenon With chloro-trimethyl-silane in tetrahydrofuran; pentane
T=-78°C; 0.0833333 h; Inert atmosphere;
参考文献
Schnermann, Martin J.; Untiedt, Nicholas L.; Jimenez-Oses, Gonzalo; Houk, Kendall N.; Overman, Larry E.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 38 p. 9581 - 9586
Angew. Chem., 2012 , vol. 124, # 38 p. 9719 - 9724,6