2-[4-(甲氧基甲氧基)苯基]-4,4,5,5-四甲基-1,3,2-二噁硼烷合成路线 （共 5 条）
反应条件
1: 4-[4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl]-phenol With sodium hydride in N,N-dimethyl-formamide; mineral oil
T=0°C; 0.166667 h;
2: chloromethyl methyl ether in N,N-dimethyl-formamide; mineral oil
1 h;
参考文献
TAKEDA PHARMACEUTICAL COMPANY LIMITED; RAKER, Joseph; TANIGUCHI, Takahiko; YOSHIKAWA, Masato; HASUI, Tomoaki; KUNITOMO, Jun
Patent: WO2012/18909 A1, 2012 ;
Location in patent: Page/Page column 165 ;
WO 2012/018909 A1
反应条件
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium acetate
12 h; Inert atmosphereReflux;
参考文献
Kikuchi, Haruhisa; Matsuo, Yusuke; Katou, Yasuhiro; Kubohara, Yuzuru; Oshima, Yoshiteru
Tetrahedron, 2012 , vol. 68, # 43 p. 8884 - 8889
反应条件
bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I) in octane
T=100°C; 24 h; Inert atmosphereSealed tube;
参考文献
Yamazaki, Kenji; Kawamorita, Soichiro; Ohmiya, Hirohisa; Sawamura, Masaya
Organic Letters, 2010 , vol. 12, # 18 p. 3978 - 3981
反应条件
1: N-ethyl-N,N-diisopropylamine / dichloromethane / 20 °C
2: potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct / 12 h / |Inert atmosphere; |Reflux
View Scheme
参考文献
Kikuchi, Haruhisa; Matsuo, Yusuke; Katou, Yasuhiro; Kubohara, Yuzuru; Oshima, Yoshiteru
Tetrahedron, 2012 , vol. 68, # 43 p. 8884 - 8889
反应条件
1: in tetrahydrofuran; hexane
1 h; Inert atmosphere;
2: With acetic acid in tetrahydrofuran; hexane
Inert atmosphere;
参考文献
Steinke, Nelli; Jahr, Michael; Lehmann, Matthias; Baro, Angelika; Frey, Wolfgang; Tussetschlaeger, Stefan; Sauer, Sven; Laschat, Sabine
Journal of Materials Chemistry, 2009 , vol. 19, # 5 p. 645 - 654
