in hexane; cyclohexane
to p-bromotoluene (1.02 mmol) and Me3SnH (2.04 mmol) in hexane at 0°C added LDA (1 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;
参考文献
Reimann, Werner; Kuivila, Henry G.; Farah, Dan; Apoussidis, Theodorus
Organometallics, 1987 , vol. 6, p. 557 - 565
dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide
to a soln. of complex in DMF at room temp. under Ar was added a norbornene soln. , then aryltin trichloride was added dropwise, the soln. was heated at 55°C for 2 h, cooled to room temp. treated with CH3MgI for 1 h; HCl was added, poured into water, extd. with ether, dried over Na2SO4, evapd., silica gel chromy., GPC (chloroform); 8percent mixt. of isomers (88:12);
in toluene
mixt. of Sb and Sn deriv. was allowed to stand in an evacuated glass ampoule at room temp. for 24 h; crystals of (p-Tol)4SbCl filtered off; filtrate evapd; residue chromd. on SiO2; identified by elem. anal.;
参考文献
Sharutin; Sharutina; Senchurin; Kovaleva; Shcherbakov; Gladyshev
Russian Journal of General Chemistry, 2000 , vol. 70, # 1 p. 64 - 65
Buchman, O.; Grosjean, M.; Nasielski, J.
Bulletin des Societes Chimiques Belges, 1962 , vol. 71, p. 467 - 472
Full Text Show Details
Kula, M. R.; Amberger, E.; Mayer, K. K.
Chemische Berichte, 1965 , vol. 98, p. 634 - 637
in tetrahydrofuran
LiSnMe3 added to p-MeC6H4SnEt3 in THF, stirred at 50°C for 30 min, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products determined by GLC;
参考文献
Mochida, Kunio
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3299 - 3306
