(R)-2-苄基-5-戊烯酸合成路线 (共 4 条)
反应条件
lithium hydroxide; dihydrogen peroxide in tetrahydrofuran
T=20°C; 4 h;
参考文献
Tredwell, Matthew; Luft, Jennifer A. R.; Schuler, Marie; Tenza, Kenny; Houk, Kendall N.; Gouverneur, Veronique
Angewandte Chemie - International Edition, 2008 , vol. 47, # 2 p. 357 - 360
反应条件
potassium phosphate buffer; Rhodococcus erythropolis AJ270 cells in water
T=30°C; pH=7.0; 5.3 h;
参考文献
Gao, Ming; Wang, De-Xian; Zheng, Qi-Yu; Huang, Zhi-Tang; Wang, Mei-Xiang
Journal of Organic Chemistry, 2007 , vol. 72, # 16 p. 6060 - 6066
反应条件
boron tribromide; N-ethyl-N,N-diisopropylamine; N,N'-[(1S,2S)-1,2-diphenylethane-1,2-diyl]bis[3,5-bis(trifluoromethyl)-benzenesulfonamide] in dichloromethane
1.) -78 deg C, 24 h, 2.) -20 deg C, 14 d; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Corey; Lee, Duck-Hyung
Journal of the American Chemical Society, 1991 , vol. 113, # 10 p. 4026 - 4027
反应条件
1.) decaline, 150 deg C, 3 h; 2.) 10percent HCl, 95 deg C, 6 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Kurth, Mark J.; Decker, Owen H. W.; Hope, Hakon; Yanuck, Michael D.
Journal of the American Chemical Society, 1985 , vol. 107, # 2 p. 443 - 448