2,2,2-三甲基苯乙酮合成路线 （共 203 条）
反应条件
thionyl chloride; 1,1-dimethylethylmagnesium chloride
1.) diethyl ether, -78 deg C 2.) r.t., 2 h; Yield given. Multistep reaction;
参考文献
Brewster et al.
Journal of the American Chemical Society, 1954 , vol. 76, p. 6368,6369
反应条件
aluminium trichloride; zinc in acetonitrile
T=70°C; 20 h;
参考文献
Grant, Anya A.; Allukian, Myron; Fry, Albert J.
Tetrahedron Letters, 2002 , vol. 43, # 24 p. 4391 - 4393
反应条件
aluminium trichloride; zinc in acetonitrile
T=70°C; 20 h;
参考文献
Grant, Anya A.; Allukian, Myron; Fry, Albert J.
Tetrahedron Letters, 2002 , vol. 43, # 24 p. 4391 - 4393
反应条件
formic acid; mercury; zinc in ethanol
1 h; Heating;
参考文献
Hiegel, Gene A.; Carney, John R.
Synthetic Communications, 1996 , vol. 26, # 14 p. 2625 - 2631
反应条件
aluminium trichloride in benzene
T=50°C; 98 h;
参考文献
Fernandez-Monreal, Maria C.; Ruiz, Maria P.; San-Roman, Julio
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1988 , p. 1983 - 1988
反应条件
hydroxylamine hydrochloride; sodium acetate in methanol; water
Heating;
参考文献
Dunina, Valery V.; Kuz'mina, Lyudmila G.; Kazakova, Marina Yu.; Gorunova, Ol'ga N.; Grishin, Yury K.; Kazakova, Elena I.
European Journal of Inorganic Chemistry, 1999 , # 6 p. 1029 - 1039
反应条件
potassium hydroxide in xylene
6 h; Heating;
参考文献
Calas,M. et al.
Bulletin de la Societe Chimique de France, 1973 , p. 2079 - 2086
参考文献
Thoraval, J. Y.; Nagai, W.; Yeung Lam Ko, Y. Y. C.; Carrie, R.
Tetrahedron, 1990 , vol. 46, # 11 p. 3859 - 3868
反应条件
1: 85 percent / diethyl ether / 20 h / Heating
2: 64 percent / hydrogen / 10 percent Pd/C / ethanol / 3675.3 Torr
View Scheme
参考文献
Andersson, Sven; Drakenberg, Torbjoern
Organic Magnetic Resonance, 1983 , vol. 21, # 12 p. 730 - 744
反应条件
1: zinc; benzene
2: aq.-ethanolic potassium carbonate
3: acetyl chloride
4: acetic acid; hydrogen bromide
View Scheme
参考文献
Tsatsas
Annales de Chimie (Cachan, France), 1946 , vol. <12> 1, p. 342,387
Bulletin de la Societe Chimique de France, 1947 , p. 1011,1012
