2,4,6-三甲基苯甲酰氯合成路线 （共 72 条）
参考文献
Wegmann, Helmut; Steglich, Wolfgang
Chemische Berichte, 1981 , vol. 114, # 7 p. 2580 - 2594
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine
Substitution; Heating;
参考文献
Yaguchi, Kyoko; Endo, Yasuyuki
Tetrahedron Letters, 1999 , vol. 40, # 41 p. 7351 - 7354
反应条件
triethylamine in diethyl ether
参考文献
Reitz,D.B. et al.
Journal of the American Chemical Society, 1978 , vol. 100, p. 5428 - 5436
反应条件
1: Py / CHCl3
2: Li / tetrahydrofuran
View Scheme
参考文献
Katzenellenbogen,J.A.; Lenox,R.S.
Journal of Organic Chemistry, 1973 , vol. 38, p. 326 - 335
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine
Substitution; Heating;
参考文献
Yaguchi, Kyoko; Endo, Yasuyuki
Tetrahedron Letters, 1999 , vol. 40, # 41 p. 7351 - 7354
参考文献
Kadesch
Journal of the American Chemical Society, 1942 , vol. 64, p. 726
反应条件
diethyl ether; silver nitrate
anschliessendes Behandeln des Reaktionsgemisches mit Hexan-1-ol;
参考文献
Freeman et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 6062
反应条件
1: With sodium in toluene
T=105°C;
2: With chlorobenzene in toluene
T=45 - 50°C;
3: phenylphosphonous dichloride; 2,4,6-trimethylbenzoyl chloride With water; butan-1-ol
more than 3 stages;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/14606 A1, 2005 ;
Location in patent: Page/Page column 9-10 ;
参考文献
CIBA SPECIALTY CHEMICALS HOLDING INC.
Patent: WO2005/14605 A1, 2005 ;
Location in patent: Page/Page column 39-40 ;
反应条件
1: 1,2-Diphenyl-1,2-bis(trimethylsilyl)diphosphan With sodium in toluene
2: 2,4,6-trimethylbenzoyl chloride in toluene
Further stages.;
参考文献
Gruetzmacher, Hansjoerg; Geier, Jens; Stein, Daniel; Ott, Timo; Schoenberg, Hartmut; Sommerlade, Reinhard H.; Boulmaaz, Souad; Wolf, Jean-Pierre; Murer, Peter; Ulrich, Thomas
Chimia, 2008 , vol. 62, # 1-2 p. 18 - 22
