1: With methanesulfonic acid; zinc in tetrahydrofuran Blaise reaction; 0.5 h; 2: With hydrogenchloride in tetrahydrofuran
参考文献
Shin, Hyunik; Choi, Bo Seung; Lee, Ki Kon; Choi, Hyeong-Wook; Chang, Jay Hyok; Lee, Kyu Woong; Nam, Do Hyun; Kim, No-Soo
Synthesis, 2004 , # 16 p. 2629 - 2632
lt;(η5-C5H5)Fe(CO)2(THF)gt;+lt;BF4gt;- in dichloromethane T=0°C; 8 h; other temperature; iron Lewis acid catalyzed reaction of aromatic aldehydes with ethyl diazoacetate; 1,2-aryl shift; effect of the subtituents in aldehyde aromatic ring on selectivity; formation of intermediate complexes; reaction mechanism; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 63, # 10 p. 3333 - 3336
