catalyst: 18-crown-6 in tetrahydrofuran refluxing KF with catalytic amt. of crown for 20 min, dropwise addn. of 0.1 equiv. of N3P3Cl6, refluxing (1 h); fractional distn.;
参考文献
Walsh et al.
Inorganica Chimica Acta, 1976 , vol. 16, p. L9
in nitrobenzene heating a soln. of (NPCl2)3 in C6H5NO2 with solid 90 percent KSO2F on refluxing; react. starting at 100. degree.C under evolution of gas;; condensation of (NPCl2)3 and formed SO2 on cooling with dry ice; isolation on distg. at 0 °C;;
in not given byproducts: N4P4F4Cl4; react. of (NPCl2)3 with PbF2;; freezing out, dissolving in petroleum ether; fractionation, at 50 °C (NPF2)3, at 70-95 °C (NPF2)4;;
in neat (no solvent) byproducts: Cl2; react. starting at 120 °C, react. at higher temp. with detonation; formation of a grey-black compound with composition PN impured with Cl2;;
参考文献
Renaud, P.
Bulletin de la Societe Chimique de France, 1933 , vol. 53, p. 692 - 697
Full Text Show Details
Gmelin Handbook: P: MVol.C, 243, page 555 - 557
in acetone react. of a soln. of (PNCl2)3 in acetone (1/500 mol in 6 ml) with a soln. of NaN3 in a stream of N2;; formation of an oily compound with composition P3N21;;
参考文献
Grundmann, C.; Raetz, R.
Zeitschrift fuer Naturforschung, 1955 , vol. 10 b, p. 116 - 117
Full Text Show Details
Gmelin Handbook: P: MVol.C, 243, page 555 - 557
in neat (no solvent) byproducts: Cl2; react. starting at 120 °C, react. at higher temp. with detonation; formation of a grey-black compound with composition PN impured with Cl2;;
参考文献
Renaud, P.
Bulletin de la Societe Chimique de France, 1933 , vol. 53, p. 692 - 697
Full Text Show Details
Gmelin Handbook: P: MVol.C, 243, page 555 - 557
