9,10-环氧-1,5-环十二碳二烯合成路线 （共 19 条）
反应条件
hydrogen; lithium iodide; nickel 1.) 140 deg C, 4 h, 2.) ethanol, 20 deg C, 1 atm, 30 h; Yield given. Multistep reaction;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 7.2 p. 1291 - 1294
Zhurnal Organicheskoi Khimii, , vol. 26, # 7 p. 1497 - 1500
反应条件
hydrogen; 0.5 Pt/Al2O3 T=140°C; P=37503.8 Torr; 2 h;
参考文献
Ube Industries, Ltd.; EMS-Chemie AG
Patent: EP1433771 A1, 2004 ;
Location in patent: Page 5-6; 8-9 ;
反应条件
hydrogen; palladium on silica gel T=160 - 175°C; P=2205.22 - 6615.66 Torr; 2 - 5 h;
参考文献
US6335472 B1, ;
Example 8-10 ;
反应条件
hydrogen; 5percent Pd/C(en) in tetrahydrofuran T=20°C; Catalytic hydrogenation; P=3800.26 Torr; 24 h; Title compound not separated from byproducts.;
参考文献
Sajiki, Hironao; Hattori, Kazuyuki; Hirota, Kosaku
Chemistry - A European Journal, 2000 , vol. 6, # 12 p. 2200 - 2204
反应条件
hydrogen; platinum on activated charcoal
参考文献
UBE INDUSTRIES, LTD.
Patent: US2013/5960 A1, 2013 ;
Location in patent: Page/Page column 25-26 ;
反应条件
hydrogen; palladium on silica gel T=160 - 175°C; P=2205.22 - 6615.66 Torr; 2 - 5 h;
参考文献
UBE Industries, Ltd.
Patent: US6335472 B1, 2002 ;
Location in patent: Example 13 ;
反应条件
lithium iodide T=200 - 260°C; 2 h; Conversion of starting material;
参考文献
Ube Industries, Ltd.
Patent: US6388140 B2, 2002 ;
Location in patent: Page column 7-10 ;
反应条件
1: 88 percent / conc. aq. HCl / CHCl3 / 5 h / Ambient temperature
2: 70 percent / K2Cr2O7, H2SO4 / diethyl ether; H2O / 0.25 h / 15 °C
View Scheme
参考文献
Haufe, Guenter
Synthesis, 1983 , # 3 p. 235 - 237
反应条件
1: hydrogen / platinum on activated charcoal
2: lithium iodide / 230 °C
3: hydroxylammonium sulphate; ammonia; sulfuric acid; ammonium sulfate / toluene; water / 85 °C / pH 4 - 5.8 / Industry scale
View Scheme
参考文献
UBE INDUSTRIES, LTD.
Patent: US2013/5960 A1, 2013 ;
